Dense Gases, Liquids and Solids

  • 4.5
Approx. 5 hours to complete

Course Summary

Explore the behavior of dense gases, liquids, and solids in this course. Learn about the thermodynamic principles that govern the behavior of these substances and gain a deeper understanding of their physical properties.

Key Learning Points

  • Learn about the behavior of dense gases, liquids, and solids
  • Understand the thermodynamic principles that govern their behavior
  • Gain a deeper understanding of their physical properties

Related Topics for further study


Learning Outcomes

  • Understand the behavior of dense gases, liquids, and solids
  • Apply thermodynamic principles to explain the behavior of these substances
  • Analyze physical properties of dense gases, liquids, and solids

Prerequisites or good to have knowledge before taking this course

  • Basic knowledge of thermodynamics
  • Background in chemistry or physics

Course Difficulty Level

Intermediate

Course Format

  • Online self-paced course
  • Video lectures
  • Assignments and quizzes

Similar Courses

  • Thermodynamics: An Engineering Approach
  • Physical Chemistry: Fundamentals and Applications

Related Education Paths


Notable People in This Field

  • Dr. Bill Nye
  • Dr. Michio Kaku

Related Books

Description

Course 4 of Statistical Thermodynamics addresses dense gases, liquids, and solids. As the density of a gas is increased, intermolecular forces begin to affect behavior. For small departures from ideal gas behavior, known as the dense gas limit, one can estimate the change in properties using the concept of a configuration integral, a modification to the partition function. This leads to the development of equations of state that are expansions in density from the ideal gas limit. Inter molecular potential energy functions are introduced and it is explored how they impact P-V-T behavior. As the density is increased, there is a transition to the liquid state. We explore whether this transition is smooth or abrupt by examining the stability of a thermodynamic system to small perturbations. We then present a brief discussion regarding the determination of the thermodynamic properties of liquids using concept of the radial distribution function (RDF), and how the function relates to thermodynamic properties. Finally, we explore two simple models of crystalline solids.

Outline

  • The Configuration Integral
  • Dense Gases: The Configuration Integral and The Fundamental Relation
  • Property Relations including the Virial Equation of State
  • Potential Energy Functions
  • Empirical Equations of States
  • Dense Gases The Configuration Integral and The Fundamental Relation
  • Property Relations including the Virial Equation of State
  • Potential Energy Functions
  • Empirical Equations of State
  • Thermodynamic Stability
  • The Basics of Thermodynamic Stability
  • First Order Phase Transitions and Finding the Vapor Dome
  • Gibb's Phase Rule
  • The Basics of Thermodynamic Stability
  • First Order Phase Transitions and Finding the Vapor Dome
  • Gibb's Phase Rule
  • Problem 11.1
  • The radial distribution function, thermodynamic properties, and MD simulations of liquid properties
  • Liquids: Cells, The Radial Distribution Function and Thermodynamic Properties
  • Molecular Dynamics
  • Determining g(r) from Molecular Dynamics
  • Liquids: Cells, The Radial Distribution Function and Thermodynamic Properties
  • Molecular Dynamics
  • Determining g(r) from Molecular Dynamics
  • Crystalline Solids
  • Solids: The Einstein Crystal
  • The Debye Crystal
  • Solids and the Einstein Crystal
  • The Debye Crystal
  • Problem 10.2
  • Problem 10.1
  • Problem 10.4

Summary of User Reviews

Discover the properties of dense gases, liquids, and solids in this course. Students have found this course to be informative and engaging, with many praising the practical applications of the material covered.

Key Aspect Users Liked About This Course

The practical applications of the material covered

Pros from User Reviews

  • Informative and engaging course
  • Practical applications of the material covered
  • Good for beginners and experts alike
  • Excellent instruction and well-organized content
  • High-quality video lectures

Cons from User Reviews

  • Some technical issues with the course platform
  • Not enough hands-on exercises
  • Some sections may be too basic for those with prior knowledge
  • No interaction with the instructor or other students
  • Limited feedback on assignments
English
Available now
Approx. 5 hours to complete
John W. Daily
University of Colorado Boulder
Coursera

Instructor

John W. Daily

  • 4.5 Raiting
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